Selective sublimation/desublimation separation of ZrF4 and HfF4
نویسندگان
چکیده
منابع مشابه
Preparation and structures of coordination complexes of the very hard Lewis acids ZrF4 and HfF4.
[MF(4)(dmso)(2)] (M = Zr or Hf) and [MF(4)(dmf)(2)], prepared by dissolving MF(4)·nH(2)O in the appropriate solvent, have been used as synthons for a range of complexes of these otherwise intractable tetrafluorides. These reagents react with OPR(3) (R = Me or Ph) or OAsPh(3) (L) in anhydrous CH(2)Cl(2) to form six-coordinate [MF(4)L(2)] which exist as a mixture of cis (predominant form) and tra...
متن کاملEffect of TiF4, ZrF4, HfF4 and AmF on erosion and erosion/abrasion of enamel and dentin in situ.
OBJECTIVE This in situ study aimed to analyse the impact of different tetrafluorides (TiF(4), ZrF(4) and HfF(4)) and AmF on erosion and erosion plus abrasion of enamel and dentin. DESIGN Ten volunteers took part in this crossover and double-blind study performed in 8 phases of each 3 days. In each phase, 2 bovine enamel and 2 dentin specimens were fixed in intraoral appliances. One enamel and...
متن کاملassessment of deep word knowledge in elementary and advanced iranian efl learners: a comparison of selective and productive wat tasks
testing plays a vital role in any language teaching program. it allows teachers and stakeholders, including program administrators, parents, admissions officers and prospective employers to be assured that the learners are progressing according to an accepted standard (douglas, 2010). the problems currently facing language testers have both practical and theoretical implications but the first i...
Effects of pH and pulp potential on the selective separation of Molybdenite from the Sungun Cu-Mo concentrate
In this research, selective flotation of Mo from the Sungun Cu-Mo concentrate was evaluated in different operating conditions. It was found that the addition of 16 kg/t Na2S into flotation pulp and aeration decreased rapidly the initial oxidized- reduction potential (ORP) of the pulp from +228mV to -597 mV (with reference to standard Ag/AgCl electrode) and increasing the amount of Na2S by 50kg/...
متن کاملApplication of Mixed Micelle-Mediated Extraction for Selective Separation and Spectrophotometric Determination of P-Aminophenol Impurity in Pharmaceutical Formulations
A procedure for separation/preconcentration of para-aminophenol (PAP) in pharmaceutical formulation, based on cloud point extraction (CPE) as a prior step to determination by UV-Vis spectrophotometry has been developed. The analyte reacted with 4-dimethylamino benzaldehyde (DAB) in acidic media to form a shift base, which were separated and preconcentrated in a mixed micelle of the anionic surf...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the Southern African Institute of Mining and Metallurgy
سال: 2017
ISSN: 2411-9717
DOI: 10.17159/2411-9717/2017/v117n10a3